Mineralogical,geochemical and microfabric evidences of gypsum crusts: a case study from Budapest     

Siegfried Siegesmund  Akos Török  Andre Hüpers  Christian Müller  Werner Klemm 《Environmental Geology》2007,52(2):385-397

High levels of SO₂ and particulate pollution enable the rapid development of gypsum-rich weathering crusts in Budapest. Two types of white crusts, thin and thick ones, and two forms of black crusts, laminar and framboidal ones, were studied in limestone buildings of the parliament and Citadella. The percentage of crust cover and damage categories were documented on selected walls. Petrographic, XRD, XRF and sulphur isotope analyses were performed under laboratory conditions to understand the mechanism of crust formation. White crusts found both on exposed and sheltered walls display a calcite-rich layer with gypsum, while black crusts are enriched with gypsum. The sulphur isotopic composition of white and black crusts overlaps, but the crusts are slightly enriched in heavy isotopes compared to rainwater. S content, Si/Al ratios and particulates in black crusts suggest that air pollution (SO₂, dust) contributes to black crust formation. The accumulation of sulphur and Zn enrichment of white crusts were also documented indicating that under high pollution levels, even these compound can accumulate on exposed facades.  相似文献   

Microseismicity of the ultraslow-spreading Gakkel ridge, Arctic Ocean: a pilot study     

Vera Schlindwein  Christian Müller  Wilfried Jokat 《Geophysical Journal International》2007,169(1):100-112

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A sediment budget for a cultivated floodplain in tropical North Queensland,Australia     

Fleur Visser  Christian H. Roth  Robert Wasson  Gerard Govers 《地球表面变化过程与地形》2007,32(10):1475-1490

Sugarcane is grown on the floodplains of northern Queensland adjacent to the Great Barrier Reef lagoon. Sediment and nutrient loss from these sugarcane areas is considered a potential threat to coastal and marine ecosystems. To enable sugarcane cultivation, farmers have structured the landscape into different elements, comprising fields, water furrows, ‘headlands’ and drains. In order to apply appropriate management of the landscape and reduce export of sediment, it is important to identify which of these elements act as sediment sources or sinks. In this study erosion and deposition rates were measured for the different landscape elements in a subcatchment of the Herbert River and used to create a sediment budget. Despite large uncertainties, the budget shows that the floodplain area is a net source of sediment. Estimated sediment export varies between 2 and 5 t ha^?1 y^?1. The relative importance of the landscape elements as sediment sources could also be determined. Plant cane is identified as the most important sediment source. Water furrows generate most sediment, but are a less important source of exported sediment due to their low connectivity. Headlands and minor drains act as sediment traps. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Advection in plankton models with variable elemental ratios     

James R. Christian 《Ocean Dynamics》2007,57(1):63-71

As ocean biogeochemical models evolve to permit the elemental composition of plankton populations and dissolved organic matter to vary, each element is normally assigned a separate state variable, which is advected and mixed independently of the others. In a population of cells with varying elemental quotas, the proper currency of the advection operator is subpopulations of similar cells. The spatial gradient in total C, N, or P summed over the spectrum of such subpopulations is identical to that calculated for the population means, so treating the various elements as independent should generally be a valid approximation. However, errors can arise in high-order advection schemes with nonlinear corrector terms, which are not additive across the subpopulations. Some numerical examples indicate that these errors are relatively small [O(10⁻³–10⁻⁴)] but can be as high as O(10⁻²) in certain cases. As grid resolution varies, the error scales approximately to the Courant number.  相似文献   

0.99999999 confidence ambiguity resolution with GPS and Galileo     

Christian Tiberius  Thomas Pany  Bernd Eissfeller  Peter Joosten  Sandra Verhagen 《GPS Solutions》2002,6(1-2):96-99

In this short contribution it is demonstrated how integer carrier phase cycle ambiguity resolution will perform in near future, when the US GPS gets modernized and the European Galileo becomes operational. The capability of ambiguity resolution is analyzed in the context of precise differential positioning over short, medium and long distances. Starting from dual-frequency operation with GPS at present, particularly augmenting the number of satellites turns out to have beneficial consequences on the capability of correctly resolving the ambiguities. With a 'double' constellation, on short baselines, the confidence of the integer ambiguity solution increases to a level of 0.99999999 or beyond. Electronic Publication  相似文献   

Genetic differentiation of populations of Greenlandic Arctic fox     

Pia G. Meinke  Christian M. O. Kapel  Peter Arctander 《Polar research》2001,20(1):75-83

Most microsatellites are very polymorphic. This makes them powerful markers for observing genetic differentiation between closely related populations. The population structure of the Greenlandic Arctic fox ( Alopex lagopus ) was studied genetically by analysing six polymorphic microsatellite loci of 75 foxes from four populations in different parts of Greenland. Genotypes were determined at the six loci for most of the individuals. Population differentiation was quantified in three different ways both within the total population and pairwise between all populations. The tests were Fisher's exact test, Rho estimates and Fst estimates, all of which supported a highly significant subdivision of the total population, and they showed significant differentiation in allele frequencies between all pairs of localities. It is concluded that the known long-distance migration of the Greenlandic Arctic fox has not resulted in complete genetic mixing of the populations. Fisher's exact test was also used to estimate levels of genetic differentiation between the two colour morphs: white and blue. No difference was found between allele frequencies of the two color morphs in any of the locations, and it was concluded that the white and blue morphs of the Greenlandic Arctic fox share the same habitat, at least during the mating season.  相似文献   

Transport and deposition of large woody debris in streams: a flume experiment   总被引：4，自引：0，他引：4  

Christian A. Braudrick  Gordon E. Grant 《Geomorphology》2001,41(4)

Large woody debris (LWD) is an integral component of forested streams of the Pacific Northwest and elsewhere, yet little is known about how far wood is transported and where it is deposited in streams. In this paper, we report the results of flume experiments that examine interactions among hydraulics, channel geometry, transport distance and deposition of floating wood. These experiments were carried out in a 1.22-m-wide×9.14-m-long gravel bed flume using wooden dowels of various sizes as surrogate logs. Channel planforms were either self-formed or created by hand, and ranged from meanders to alternate bars. Floating pieces tended to orient with long axes parallel to flow in the center of the channel. Pieces were deposited where channel depth was less than buoyant depth, typically at the head of mid-channel bars, in shallow zones where flow expanded, and on the outside of bends. We hypothesize that the distance logs travel may be a function of the channel's debris roughness, a dimensionless index incorporating ratios of piece length and diameter to channel width, depth and sinuosity. Travel distance decreased as the ratio of piece length to both channel width and radius of curvature increased, but the relative importance of these variables changed with channel planform. Large pieces can move further than our debris roughness models predict if greater than 50% of the active channel area is deeper than the buoyant depth of the piece, or if momentum is high enough to carry pieces across shallows. Our debris roughness model allows first-order prediction of the amount of wood transport under various channel geometries.  相似文献   

Dissolved Humic Substances Can Directly Affect Freshwater Organisms     

Stephan Pflugmacher  Linda Fay Tidwell  Christian E. W. Steinberg 《洁净——土壤、空气、水》2001,29(1):34-40

Direct effects of pure humic substance (BS1 FA) on three different aquatic organisms (Ceratophyllum demersum, Dreissena polymorpha, and Chaetogammarus ischnus) were demonstrated in this study. Exposure to environmentally relevant concentrations (0.5 mg/L) of this humic substance led to the activation of the microsomal and soluble glutathione S‐transferase (GST) in Ceratophyllum demersum. Exposure to 3‐chlorobiphenyl showed also an elevation of GST activity, which is due to the proposed detoxication metabolism of these chlorinated biphenyl. Coexposure to a mixture of 3‐chlorobiphenyl and BS1 FA showed a reduction of enzyme elevation, but still significant over an untreated control. The direct impact of humic substances seems not to be restricted to a specific class of organisms.  相似文献   

An Overview of Dissolved and Suspended Matter Fluxes in the Loire River Basin: Natural and Anthropogenic Inputs   总被引：7，自引：0，他引：7  

Cécile Grosbois  Philippe Négrel  Daniel Grimaud  Christian Fouillac 《Aquatic Geochemistry》2001,7(2):81-105

The spatial and temporal distributions of major elements were investigated in the surface waters and in associated suspended matter at two sites of the upper Loire basin (Orleans and Brehemont) between 1995 and 1998.According to geochemical and isotopic patterns, the dissolved load appears to result from a process of mixing rainwater inputs, weathering processes of carbonate and silicate bedrock, and agricultural and urban inputs. Natural inputs influence 60% of water chemical composition at both sites. Annual dissolved fluxes were estimated to be 1300 10³ t/y at Orleans and 1620 10³ t/y at Brehemont. Major elements are transported mainly in the dissolved fraction. After correcting for atmospheric and anthropogenic inputs, the silicate specific export rate was calculated to be 11 t/y/km² throughout the basin and the carbonate specific export rate to be from 47 t/y/km² at Orleans to 23 t/y/km² at Brehemont.The suspended load appears to result from at least two particle reservoirs: a silicate reservoir and a carbonate reservoir. The silicate reservoir has a detrital origin, mainly during periods of high flow, while the carbonate reservoir has a detrital origin during periods of high flow and an authigenic origin during periods of low flow. Of the total annual flow of suspended matter, this authigenic material represents 16% at Orleans, 25% at Brehemont and 37% in the fluvial part of the estuary. After correcting authigenic inputs, the specific export rate due to mechanical weathering was estimated to be 8 t/y/km² throughout the Loire basin.  相似文献   

Biotransformation at 10° C of Di-n-Butyl Phthalate in Subsurface Microcosms     

Christian Chauret  William E. Inniss  Colin I. Mayfield 《Ground water》1996,34(5):791-794

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